Sarah Salloum

Low-Temperature Synthesis of Thermoelectric Group 14 and Group 15 Chalcogenide Nanoparticles by Thermal Decomposition of Tailor-Made Metal Organic Precursors (MOPs) in Ionic Liquids (ILs)

  • Develop new reactive polynuclear IL precursors for the synthesis of phase pure nanomaterials of group 14 and group 15 chalcogenides (SnE, PbE, Sb2E3, Bi2E3, (SbxBi1-x)2E3, (BixSb1-x)2 (TeySe1-y)3; E = Se, Te)
  • Incorporate heavy metal dopants (Ag, In, Tl) to improve TE properties
  • Synthesize NPs using alternative ILs of promising cation/anion combinations to increase the solubility of MOPs and lower the binding affinity of the IL
  • Characterization of NPs via PXRD, SEM, TEM, and EDX

Publications

Salloum, S.; Bendt, G.; Heidelmann, M.; Loza, K.; Bayesteh, S.; Sepideh Izadi, M.; Kawulok, P.; He, R.; Schlörb, H.; Perez, N.; Reith, H.; Nielsch, K. ; Schierning, G.; Schulz, S., Influence of nanoparticle processing on the thermoelectric properties of (BixSb1−X)2Te3 ternary alloys. ChemOpen 2021, 10, 189-198, doi.org10.1002/open.202000257.

Loor, M.; Salloum, S.; Kawulok, P.; Izadi, S.; Bendt, G.; Guschlbauer, J.; Sundermeyer, J.; Pérez, N.; Nielsch, K.; Schierning, G.; Schulz, S., Ionic liquid-based low-temperature synthesis of phase-pure tetradymite-type materials and their thermoelectric properties. Inorg. Chem. 2020, 59, 3428-3436, https://doi.org/10.1021/acs.inorgchem.9b03060.

Sarah Salloum
sarah.salloum(at)uni-due.de

Group: Prof. S. Schulz,  Faculty of Inorganic Chemistry, Universität Duisburg-Essen