Julia Krüger

A mechanistical study on reduction reactions of group 15 compounds with low valent group 13 organyls

  • Syntheses and reactivity studies of group 13/15 compounds by using sterically demanding ligands
  • Characterization of the compounds by using NMR and IR spectroscopy as well as single crystal x-ray diffractometry
  • Performance of quantum chemical calculations to generate an impression of the electronic properties and comparison with the experimental data
  • Investigations to understand the reaction mechanism via in situ NMR spectroscopy

Publications

Krüger, J.; Wölper, C.; Schulz, S., From π-bonded gallapnictenes to nucleophilic, redox-active metal-coordinated pnictanides. Angew. Chem., Int. Ed., 2021, 60, 3572-3575, https://doi.org/10.1002/anie.202013618. German Edition: Angew. Chem., 2021, 60, 3615-3618, https://doi.org/10.1002/ange.202013618.

Krüger, J.; Wölper, C.; Schulz, S., Stepwise Bi-Bi bond formation - From a Bi-centered radical to Bi4 butterfly and Bi8 cuneane-type clusters. Inorg. Chem. 2020, 59, 11142-11151, https://doi.org/10.1021/acs.inorgchem.0c01657.

Krüger, J.; Wölper, C.; John, L.; Song, L.; Schreiner, P. R.; Schulz, S., Syntheses, structures, and bonding analyses of carbene-stabilized stibinidenes. Eur. J. Inorg. Chem. 2019, 2019, 1669-1678, https://doi.org/10.1002/ejic.201900167.

Julia Krüger
julia.krueger(at)uni-due.de

Group: Prof. S. Schulz,  Faculty of Inorganic Chemistry, Universität Duisburg-Essen